Transition metals for lithium batteries
Theoretical Investigation of the Electrochemical Performance of …
Here we systematically investigate the electrochemical performance of a series of transition metal nitrides (TMNs) for Li–S batteries. All TMNs we investigated …
Iron (Fe, Ni, Co)-based transition metal compounds for lithium-sulfur batteries…
This review mainly focuses on the summary about iron (Fe, Ni, Co)-based transition metal compounds to anchor and catalyze LiPSs for lithium-sulfur batteries with some modification methods. Download: Download high-res image (73KB)Download: Download full-size image
Crosstalk shielding of transition metal ions for long cycling lithium–metal batteries …
Lithium–metal batteries (LMBs) comprising a lithium anode and high-specific-capacity manganese (Mn)-based cathode provide a promising high-energy-density system. However, this full cell suffers from poor cycling life under practical conditions. In this contribution, the effect of transition metal ions, e.g.,
Transition Metals Embedded Siloxene as Single-Atom Catalyst for Advanced Sulfur Host in Lithium–Sulfur Batteries…
Herein, a series of 3d transition metal single-atom embedded siloxenes (TM-SA-siloxenes) is designed and their potential in Li–S batteries is evaluated by first-principles calculations. It is found that Weiss-siloxene shows the best polysulfide anchoring ability and lowest Gibbs free energy for the sulfur reduction reaction (SRR).
Crystals | Special Issue : Lithium Transition Metal Oxides
Lithium transition metal oxides have played a critical role in the commercialization and wide scale adaptation of the lithium ... (NCA), are typically used as positive electrode materials in the lithium-ion batteries. However, these materials pose limitations in terms ...
Recent advances in transition metal chalcogenide derivatives from metal-organic frameworks for lithium-sulfur batteries …
Introduction The ever-increasing energy demand and the depletion of natural resources have led to the pursuit of alternative energy storage and conversion systems with enhanced safety, high energy, and low cost. 1 Rechargeable batteries are one of the most crucial energy-storage systems. 2, 3, 4 Although lithium-ion batteries (LIBs) …
Effects of transition metals for silicon-based lithium-ion battery …
Transition metal vanadates electrodes in lithium-ion batteries: a holistic review Energy Storage Mater., 35 ( 2021 ), pp. 169 - 191, 10.1016/j.ensm.2020.10.023 View PDF View article View in Scopus Google Scholar
Transition Metal Phosphates/Phosphonates for Lithium-Ion Batteries
Tavorite structured phosphates have the general formula LiM(PO 4)X (M―transition metal, X―O, OH, F) and can be considered as a promising cathode material for lithium-ion batteries because 2 lithium ions can …
Boosting Lean Electrolyte Lithium–Sulfur Battery Performance …
Advanced lithium-ion batteries are those that pair high-capacity lithium transition metal oxide cathodes with silicon and lithium metal, rather than just with graphite anode …
High performance ultra-thin lithium metal anode enabled by …
5 · The passivation layer that naturally forms on the lithium metal surface contributes to dendrite formation in lithium metal batteries by affecting lithium …
A cycling-insensitive recycling method for producing lithium transition metal oxide from Li-ion batteries …
Direct recycling separates and recovers both anode active materials (i.e. graphite) and cathode active materials (i.e. lithium transition metal oxides, LTMO) from Li-ion batteries without changing their structure and chemistry during the recycling process [9].
Theoretical Investigation of the Electrochemical Performance of Transition Metal Nitrides for Lithium–Sulfur Batteries …
The notorious shuttle effect caused by the soluble polysulfide intermediates and the sluggish conversion kinetics in sulfur cathodes greatly hinder the practical application of lithium–sulfur (Li–S) batteries. Here we systematically investigate the electrochemical performance of a series of transition metal nitrides (TMNs) for Li–S …
Transition metals for stabilizing lithium metal anode: advances …
Transition metals (TMs) are lithiophilic materials that effectively stabilize lithium metal anode (LMA) and inhibit dendrite growth. Herein, the growth of lithium dendrites and the performance of TMs in stabilizing lithium metals are comprehensively discussed in this …
Layered 3d Transition Metal-Based Oxides for Sodium-Ion and …
2 · Layered 3d transition metal oxides, as crucial electrode materials, are essential for advanced lithium-ion (LIBs) and sodium-ion batteries (SIBs). This review thoroughly …
Virtual screening of two-dimensional selenides and transition metal doped SnSe for lithium-sulfur batteries…
As transition metal doping is frequently used for enhancing the activity of materials, we doped 2D SnSe with several transition metals and evaluated their performance. After geometric optimization, we obtained eleven stable transition metal doped SnSe: Sc-SnSe, Ti-SnSe, V-SnSe, Cr-SnSe, Mn-SnSe, Fe-SnSe, Co-SnSe, Ni …
Some transition metal (oxy)phosphates and vanadium oxides for lithium batteries
Iron and vanadium oxides have a rich structural chemistry when combined with phosphate groups; the transition metal most commonly in an octahedral coordination. The inductive effect increases the potential difference between Fe3+/Fe2+ and Li/Li+ couples in phosphate lattices relative to the pure iron oxides;
Some transition metal (oxy)phosphates and vanadium oxides for lithium batteries
Iron and vanadium oxides have a rich structural chemistry when combined with phosphate groups; the transition metal most commonly in an octahedral coordination. The inductive effect increases the potential difference between Fe 3+ /Fe 2+ and Li/Li + couples in phosphate lattices relative to the pure iron oxides; a similar behavior is found for the …
Recent Progress on Nanostructured Transition Metal Oxides As Anode Materials for Lithium-Ion Batteries …
Lithium-ion batteries (LIBs) have been broadly utilized in the field of portable electric equipment because of their incredible energy density and long cycling life. In order to overcome the capacity and rate bottlenecks of commercial graphite and further enhance the electrochemical performance of LIBs, it is vital to develop new electrode materials. …
Recent advances in transition metal chalcogenides for lithium-ion capacitors | Rare Metals …
Transition metal chalcogenides (TMCs) and TMCs-based nanocomposites have attracted extensive attention due to their versatile material species, low cost, and rich physical and chemical characteristics. As anode materials of lithium-ion capacitors (LICs), TMCs have exhibited high theoretical capacities and pseudocapacitance storage …
Transition metal sulfides as cathodes for secondary lithium batteries…
Printed in Great Britain TRANSITION METAL SULFIDES AS CATHODES FOR SECONDARY LITHIUM BATTERIES JI. TITANIUM SULFIDES G. L. HOLLECK and J. R. Daiscou. EIC Corporation, 55 Chapel Street, Newton, MA 02158, U.S.A. (Received 5 January 1977) Abstract Titanium disulfide (Ti1 taS2) and trisuffide (TiS3) were prepared …
Separation of lithium and transition metals from leachate of spent lithium-ion batteries by solvent extraction method with Versatic …
When extracting metals from the leaching liquor of spent lithium-ion batteries (LIBs), the focus of traditional methods has been putting on the separation of transition metals, i.e. manganese, cobalt and nickel, which needs a …
Transition metal vanadium oxides and vanadate materials for lithium batteries …
Transition metal vanadates (TMVs) (TM= Co, Zn, Ni, Cu, Mn, Fe, etc) have displayed outstanding electrochemical performances in lithium-ion batteries (LIBs) with intriguingly rich crystal ...
Transition Metals Embedded Siloxene as Single‐Atom Catalyst for Advanced Sulfur Host in Lithium–Sulfur Batteries…
The practical applications of lithium–sulfur batteries are presently hindered by the shuttle effect, sluggish reaction kinetics, and poor electronic conductivity of sulfur. Siloxene, a new 2D nanomaterial with three types of structures (Weiss, chain like, and Kautsky), is regarded to be a promising cathode‐supporting material for Li–S batteries. …
Review Nanostructured transition metal sulfides for lithium ion batteries…
High performance lithium batteries are in great demand for consumer electronics, electric vehicles and grid scale stationary energy storage. Transition metal sulfides based on conversion or alloying reactions have drawn much attention because of their significantly ...
Transition metal vanadates electrodes in lithium-ion batteries: A …
Transition metal vanadates (TMVs) (TM= Co, Zn, Ni, Cu, Mn, Fe, etc) have displayed outstanding electrochemical performances in lithium-ion batteries (LIBs) with intriguingly rich crystal structures, redox reactions and phase transitions. In nature, the ample valence ...
Metals | Free Full-Text | Recycling Strategies for Spent Consumer Lithium-Ion Batteries …
The most commonly used transition metal oxides are the following [21,41,42,43,44,45,46]: Lithium cobalt oxide (LiCoO 2, LCO), ... and Sabine Flamme. 2024. "Recycling Strategies for Spent Consumer Lithium …
Bifunctional Functionalized Two-Dimensional Transition Metal Borides for Fast Reaction Redox Kinetics in Lithium-Sulfur Batteries …
Whereafter, a series of polar materials including metals [14], metal oxides [15], metal sulfides [16], and metal carbides [17], [18] have been explored as sulfur hosts for Li-S batteries. Besides, Zhang et al have novelly designed a series of transition-metal doped C 6 N 2 -based sulfur hosts.
Revelation of the transition‐metal doping mechanism in lithium manganese phosphate for high performance of lithium‐ion batteries …
1 INTRODUCTION The olivine-type LiFePO 4 was first proposed by J. B. Goodenough in 1997 as a cathode material for lithium-ion batteries, and he was one of the 2019 Nobel Prize winners in Chemistry. 1-5 Subsequently, a variety of LiMPO 4 (M = Fe, Mn, Co, and Ni) materials have been proposed as excellent cathode materials. 6-15 LiMPO 4 …
Nickel‐Rich Layered Lithium Transition‐Metal Oxide …
In particular, layered, Ni-rich, lithium transition-metal oxides can deliver higher capacity at lower cost than the conventional LiCoO 2. However, for these Ni-rich compounds there are still several problems …
Electrochemical Characteristics of Layered Transition …
Layered lithium transition metal oxides, in particular, NMCs (LiNi x Co y Mn z O 2) represent a family of prominent lithium ion battery cathode materials with the potential to increase energy densities …
Metal electrodes for next-generation rechargeable batteries
Efficient storage of electrical energy is mandatory for the effective transition to electric transport. Metal electrodes — characterized by ... and rechargeable lithium metal batteries ...
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